Okafor, E.C and Okeke, Ogbonnaya James (2019) SYNTHESIS OF SOME METAL COMPLEXES WITH 1-PHENYL-3-METHYL-4-ACERTHYL-PYRAZOL-5-ONE. Chemistry, Biology and Physical Sciences Academic Journal, 1 (1). ISSN 3773 – 5391
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Abstract
The ligand; 1-pheny1-3 methyl-4-acetyl Prazol-5-one (HPMAP) may be regarded as a B-diketone. The presence of B-Carbonyol groups with atleast one proton on the carbon between the Ketonic grups, allows Keto–enol tautomerism. The enolic hydrogen is activated by the adjacent c-o groups and conjugate system can arise by a prototrophic shift. Thus, under appropriate condition with the ligand, the enolic proton is removed. The compounds which form when the proton is replaced by Zirconium, Hafnium, Uranium and Cerium metals respectively is the subject of this project.
Item Type: | Article |
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Subjects: | L Education > L Education (General) Q Science > Q Science (General) |
Divisions: | Faculty of Natural and Applied Sciences |
Depositing User: | miss ifeoma agbo |
Date Deposited: | 31 May 2019 09:53 |
Last Modified: | 31 May 2019 09:53 |
URI: | http://eprints.gouni.edu.ng/id/eprint/1614 |
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